Sulfuryl fluoride

Sulfuryl fluoride
Structure and dimensions of sulfuryl fluoride	Ball-and-stick model of sulfuryl fluoride
Names
	IUPAC name Sulfuryl fluoride
	Other names Sulfonyl fluoride; Sulfur dioxide difluoride; Sulphuryl fluoride; Sulfuryl difluoride; Vikane; Zythor
Identifiers
CAS Number	2699-79-8 ;
3D model (JSmol)	Interactive image;
ChEBI	CHEBI:39287 ;
ChemSpider	16647 ;
ECHA InfoCard	100.018.437
PubChem CID	17607;
UNII	64B59K7U6Q ;
CompTox Dashboard (EPA)	DTXSID9034945 ;
	InChI InChI=1S/F2O2S/c1-5(2,3)4 Key: OBTWBSRJZRCYQV-UHFFFAOYSA-N ; InChI=1/F2O2S/c1-5(2,3)4 Key: OBTWBSRJZRCYQV-UHFFFAOYAJ;
	SMILES FS(F)(=O)=O;
Properties
Chemical formula	SO2F2
Molar mass	102.06 g/mol
Appearance	colourless gas
Odor	odorless
Density	4.172 g/L (gas), 1.632 g/mL (liquid under compressed gas at 0 °C)
Melting point	−124.7 °C (−192.5 °F; 148.5 K)
Boiling point	−55.4 °C (−67.7 °F; 217.8 K)
Solubility in water	0.2% (0°C)
Solubility in other solvents	SO2
Vapor pressure	15.8 atm (21°C)
Structure
Coordination geometry	tetrahedral
Hazards
	Occupational safety and health (OHS/OSH):
Main hazards	neurotoxin
NFPA 704 (fire diamond)	3 0 1
	Lethal dose or concentration (LD, LC):
LC50 (median concentration)	991 ppm (rat, 4 hr)
LCLo (lowest published)	1200 ppm (mouse, 1 hr); 5000 ppm (rabbit, 1 hr)
	NIOSH (US health exposure limits):
PEL (Permissible)	TWA 5 ppm (20 mg/m3)
REL (Recommended)	TWA 5 ppm (20 mg/m3) ST 10 ppm (40 mg/m3)
IDLH (Immediate danger)	200 ppm
Related compounds
Other anions	SO2Cl2,; SO2ClF
Other cations	SeO2F2
Related compounds	SF6,; SO3; SO2F3−
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Sulfuryl fluoride (also spelled sulphuryl fluoride) is an inorganic compound with the formula SO₂F₂. It is an easily condensed gas and has properties more similar to sulfur hexafluoride than sulfuryl chloride, being resistant to hydrolysis even up to 150 °C.^[3] It is neurotoxic and a potent greenhouse gas, but is widely used as a fumigant insecticide to control termites.

^ ^a ^b ^c ^d ^e ^f NIOSH Pocket Guide to Chemical Hazards. "#0581". National Institute for Occupational Safety and Health (NIOSH).
^ ^a ^b "Sulfuryl fluoride". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).
^ Cite error: The named reference Holleman was invoked but never defined (see the help page).

[PGCH-1] ^ ^a ^b ^c ^d ^e ^f NIOSH Pocket Guide to Chemical Hazards. "#0581". National Institute for Occupational Safety and Health (NIOSH).

[IDLH-2] "Sulfuryl fluoride". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).

[Holleman-3] Cite error: The named reference Holleman was invoked but never defined (see the help page).

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